Synthesis of ZSM‐5 zeolite from fly ash by one‐pot hydrothermal method for methylene blue removal.

Using fly ash to synthesize zeolite molecular sieves can improve the reuse value of coal fly ash resources, reduce the synthesis cost of the zeolites, and protect the ecology. A novel approach was proposed to prepare zeolite socony mobil‐5 (ZSM‐5) zeolite via one‐pot hydrothermal synthesis. The mesoporous ZSM‐5 synthesized by adjusting the molar ratio of chemical reagents has higher crystallinity, larger specific surface area, and more adsorption sites. An analysis of methylene blue (MB) adsorption on mesoporous ZSM‐5 was conducted at many different adsorption parameters, including solution concentration, temperature, and duration of adsorption. The Langmuir model can objectively describe the adsorption behavior of MB on ZSM‐5, and the adsorption characteristics of MB on ZSM‐5 are better described by the pseudo‐second‐order kinetic model. The thermodynamic model provides the adsorption behavior as an endothermic reaction. [ABSTRACT FROM AUTHOR]