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Enhanced butanone chemoresistive sensor utilizing cobalt oxide nanoparticles.

Authors :
Zito, Cecilia A.
Theodoro, Reinaldo S.
Perfecto, Tarcísio M.
Sá, Bruna S.de
Vioto, Gabriel C.N.
Volanti, Diogo P.
Source :
Ceramics International. Aug2024, Vol. 50 Issue 15, p27147-27153. 7p.
Publication Year :
2024

Abstract

Detection of volatile organic compounds (VOCs), particularly 2-butanone, has become crucial due to their widespread use and associated risks to human health. In this study, we present a novel synthesis method for spinel Co 3 O 4 nanoparticles (NPs) employing a microwave-assisted hydrothermal approach followed by calcination and investigate their efficiency in VOC sensing applications. The Co 3 O 4 NPs exhibit remarkable sensitivity and selectivity towards butanone at relatively low operating temperatures. VOC-sensing experiments reveal an optimal operating temperature of 250 ° C , showcasing an advantage over existing sensors. Notably, the sensor exhibits high selectivity for butanone, with signal values 1.6–4.5 times higher than those for other VOCs, including acetaldehyde, ethanol, isopropanol, methanol, acetone, m-xylene, toluene, and benzene. Additionally, the Co 3 O 4 NPs-based sensor demonstrates high sensitivity, detecting concentrations as low as 5 ppm of butanone, with fast response/recovery times of 41/86 s for 200 ppm of butanone and robust long-term stability. These findings underscore the potential of Co 3 O 4 NPs as promising candidates for low-temperature butanone detection, which is essential for environmental and human health monitoring purposes. [Display omitted] [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
02728842
Volume :
50
Issue :
15
Database :
Academic Search Index
Journal :
Ceramics International
Publication Type :
Academic Journal
Accession number :
177652210
Full Text :
https://doi.org/10.1016/j.ceramint.2024.05.012