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Simultaneous oxidation of Mn2+ to Mn4+ by devitrification of transparent glassy Na2Ge4O9: Mn.
- Source :
-
Ceramics International . Jul2024, Vol. 50 Issue 14, p24913-24920. 8p. - Publication Year :
- 2024
-
Abstract
- To generate red emissions, manganese (IV) ions have recently gained recognition as potent non-rare-earth activators. However, the oxide and fluoride hosts that offer suitable environments for Mn4+ require careful preparation, involving precise control of reaction parameters like redox equilibrium and temperature. In the current work, we show simultaneous oxidation of Mn2+ to Mn4+ by devitrification of glassy Na 2 Ge 4 O 9 : Mn under moderate atmospheric conditions and under the argon atmosphere. The G-sample was devitrified via thermal treatment after the parent glass, which shares the same chemical formula as dilithium tetragermanate (Na 2 Ge 4 O 9), was created through the use of traditional melt-quenching (MQ). Optical spectroscopy and electron paramagnetic resonance (EPR) spectroscopic are utilized to confirm the Mn2+ oxidation to Mn4+ from glass stat to glass ceramic after thermal treatment. Due to the transition from Mn2+ to Mn4+, a sharp 668 nm emission peak is recorded whereas the red emission peaking at 611 nm monitored in glass is steadily reduced. The temperature-dependent PL spectra of the Na 2 Ge 4 O 9 :0.1Mn+4, red-emitting GC in the temperature range ∼295–490 K were recorded. The PL emission intensity decreases gradually with increasing the temperature. The technique showcased for producing Na 2 Ge 4 O 9 :Mn4+ phosphors could be expanded to synthesize other phosphors incorporating activators possessing a high oxidation state. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 02728842
- Volume :
- 50
- Issue :
- 14
- Database :
- Academic Search Index
- Journal :
- Ceramics International
- Publication Type :
- Academic Journal
- Accession number :
- 177630112
- Full Text :
- https://doi.org/10.1016/j.ceramint.2023.12.170