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Solvent-controlled structural variation of two Cd(II) compounds derived from thiophene dicarboxylate and 4-imidazol-1-yl-pyridine mixed ligands.
- Source :
-
Journal of Sulfur Chemistry . Aug2024, Vol. 45 Issue 4, p500-510. 11p. - Publication Year :
- 2024
-
Abstract
- Two solvent-controlled Cd(II) compounds, formulated as {[Cd2(Htdc)4(µ-imyp)(H2O)4]} (1), [Cd2(µ2-tdc)2(µ-imyp)(DMF)2(H2O)2]n (2) (H2tdc= 2,5-thiophenedicarboxylic acid, imyp = 4-imidazol-1-yl-pyridine and DMF = N,N-dimethylformamide) have been synthesized by reactions of Cd(NO3)2·4H2O and H2tdc with imyp in different solvents, respectively. Both compounds were then characterized by single-crystal X-ray diffraction and other physicochemical methods. In 1, partially deprotonated Htdc− anion as terminal ligand and µ-imyp ligand connect Cd2+ ions to generate a discrete structure. In 2, completely deprotonated µ2 – tdc2− anions and µ-imyp ligand link Cd2+ ions into a 1D double chain structure. Both compounds display 3D supramolecular structures through hydrogen bonding interactions. The results provided interesting insights into solvent effects on the structural formation of compounds 1 and 2. In addition, the solid-state photoluminescent properties of compounds 1 and 2 were also investigated. Two solvent-controlled Cd(II) compounds have been synthesized by reactions of Cd(NO3)2·4H2O and 2,5-thiophenedicarboxylic acid with 4-imidazol-1-yl-pyridine in the different solvents. One compound is a discrete structure, while the other compound has a 1D double chain structure. The results provided interesting insights into solvent effects on the structural formation of compounds. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 17415993
- Volume :
- 45
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- Journal of Sulfur Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 178297940
- Full Text :
- https://doi.org/10.1080/17415993.2024.2355946