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Electronic and magnetic properties of boron substituted CuFeO2 delafossite oxide.
- Source :
-
Philosophical Magazine . Jun2024, Vol. 104 Issue 11/12, p519-536. 18p. - Publication Year :
- 2024
-
Abstract
- Synchrotron x-ray diffraction (SR-XRD) and X-ray absorption fine structure spectroscopy (XAFS) were used to investigate the crystal and electronic properties of boron-substituted CuFeO2 material at room temperature. Without boron substitution, the polycrystalline structures of the trigonal (rhombohedral) ' $R\bar{3}m$ R 3 ¯ m ' CuFeO2 (87.7%) and hexagonal 'P63/mmc' (12.3%), which were also present in each sample but in different proportions, were utilised to identify the base material. XRD patterns revealed that, beyond 10% boron substitution, the metal–oxygen bonds (Fe-O and Cu-O) weakened, resulting in the formation of new tetragonal 'I41/amd' CuFe2O4 crystals. Although the CuFeO2 structure was preserved, it is conceivable that the presence of other crystal structures could lead to the formation of new features. This state arose as a result of CuFe2O4 crystallization and the impact of boron activity on the surrounding oxygen structures. By measuring magnetisation at both swept temperatures (10–300 K) and applied magnetic fields (±30 kOe), the magnetic properties of the samples were investigated. In the 10–300 K temperature range, the polycrystalline samples exhibit a ferromagnetic property without a magnetic phase transition. This suggests that replacing B with Fe in CuFe1−xBxO2 does not influence the primary magnetic property of CuFeO2. The samples' saturation magnetisation (Ms) values gradually fall as the B substitution content increases with Fe. This is because there's a chance that the non-transition metal B in CuFe1−xBxO2 will boost antiferromagnetic superexchange Cu-O interactions while lowering the p-d exchange interaction. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14786435
- Volume :
- 104
- Issue :
- 11/12
- Database :
- Academic Search Index
- Journal :
- Philosophical Magazine
- Publication Type :
- Academic Journal
- Accession number :
- 177455978
- Full Text :
- https://doi.org/10.1080/14786435.2024.2337197