Mechanistic insights of PO43− functionalized carbon nitride homojunction hydrogels in photocatalytic-self-Fenton-peroxymonosulfate system for tetracycline degradation.

[Display omitted] In this study, metal-free PO 4 3− enriched g-C 3 N 4 /g-C 3 N 4 (PGCN) homojunction alginate 3D beads were developed for in-situ H 2 O 2 production under visible light. Later, the photocatalytic-self-Fenton system was integrated with peroxymonosulfate for tetracycline degradation. Initially, the PO 4 3− enriched g-C 3 N 4 (PCN) and a homojunction composed of PCN and g-C 3 N 4 (GCN) were prepared via the wet-impregnation method. Later, PGCN homojunction was formulated into 3D alginate beads through the blend-crosslinking method. The comprehensive characterization of the homojunction beads affirmed the closer contact between the semiconductors, alteration of the bandgap, faster channelization of electron-hole pairs, and improved separation of charge carriers that attributed to higher catalytic efficacy. The PGCN beads exhibited a maximum H 2 O 2 production of 535 ± 12 µM under visible light irradiation for 60 min. The homojunction hydrogels displayed 99 ± 0.25 % tetracycline degradation in 20 min in the photocatalytic-self-Fenton-PMS system. The experimental studies also claimed a maximum chemical oxygen demand removal of 81 ± 3.6 % in 20 min with maximum reusability of beads up to 20 cycles. The Z-scheme electron migration mechanism is proposed based on the results aided by scavenger and electron spin resonance analysis. Overall, the as-synthesized alginate-supported homojunction-based photocatalytic-self-Fenton-peroxymonosulfate system is highly versatile and reusable for energy and environmental remediation. [ABSTRACT FROM AUTHOR]