Controllable preparation of wollastonite-based composite coating for highly-efficient passive daytime radiative cooling in building.

[Display omitted] • A high-performance HSEC coating is fabricated for large-scale building cooling. • The HSEC coating has high average solar reflectance (95.1%) and MIR-infrared emissivity (92.5%). • The HSEC coating realizes ambient cooling up to 4.2 °C during the daytime. • The HSEC coating shows excellent anti-contamination property and radiative stability. The building cooling has aroused widespread attention due to its significant contribution to both global warming and energy usage. To combat global warming and reduce energy consumption, an environmentally friendly beneficial alternative to electric cooling for buildings is passive daytime radiative cooling (PDRC). However, many of the reported radiative coolers still suffer from the challenge of complex preparation processes and high costs, making it difficult to scale up for building applications. Herein, the utilization of abundant and low-cost natural resources (i.e., cellulosic biomass and minerals) is strategized to produce radiative cooling material and incorporate this material into building cooling systems to boost global carbon neutrality. Guided by this concept, a hydrophobic SiO 2 /EC composite (HSEC) coating is designed by embedding nano-sized wollastonite-based SiO 2 particles into porous ethyl cellulose (EC) polymer, and subsequently through polydimethylsiloxane (PDMS) dispersion spray treatment. Benefiting from the sufficient scattering by the nano-SiO 2 particles and randomly dispersed light-scattering air voids, the resulting cooling coating shows a high solar reflectivity of 95.1 %. More importantly, the molecular vibration of the chemical in HSEC coating results in a high atmospheric window emissivity of 92.5 %. In the field test, the HSEC coating remained approximately 4.2 °C below the ambient temperature under intense solar irradiation of 412.5 W⋅m−2. This work not only offers a promising strategy for realizing the high-value utilization of wollastonite resources in building materials, but also provides a controllable approach for large-scale preparation of highly efficient radiative cooling materials to alleviate building cooling demands. [ABSTRACT FROM AUTHOR]