CO2‐Dependence of Longwave Clear‐Sky Feedback Is Sensitive to Temperature.

CO2 absorbs and emits radiation, which allows it to act both as radiative forcing and feedback. Recent work has shown CO2's feedback effect becomes dominant in hothouse climates, giving rise to a non‐monotonic climate sensitivity around 310 K. However, CO2's feedback effect in colder climates is less clear. We use a line‐by‐line model to explore the CO2‐dependence of the longwave clear‐sky feedback and identify a dividing temperature. Above 290 K, feedback increases with CO2 concentration; below 290 K, feedback decreases with CO2 concentration. We explain this dependence in terms of spectral competition under CO2 increases. In hot climates, CO2's moderate feedback replaces near‐zero feedback from the H2O bands; in cold climates, CO2's moderate feedback replaces the large feedback from the surface. Given that global mean temperature is currently close to 290 K, our results suggest that feedback CO2‐dependence is weak at present but can be important in past and future climates. Plain Language Summary: CO2 traps heat, causing warming. But CO2 also emits heat to space, acting as radiative feedback. Recent work has shown CO2's feedback effect crucially helps to stabilize very hot climates, but how does it affect present‐day Earth? We show that in hot climates, more CO2 increases Earth's feedback, while in cold climates, more CO2 decreases it. To understand why, we explain that the surface is an effective emitter, CO2 is a moderate emitter, while H2O is a poor emitter. At high temperatures, adding CO2 to the atmosphere thus replaces feedback that would have otherwise come from H2O, increasing the overall feedback; at low temperatures, adding CO2 replaces feedback that would have otherwise come from the surface, decreasing the overall feedback. Currently, Earth's global‐mean temperature falls between these two temperature regimes, where CO2's effect on feedback is nearly zero. Our results explain why CO2's impact on feedback is small now but can be significant in past or future climates. Key Points: An increase in CO2 concentration strengthens Earth's feedback in hot climates, ∂λ/∂CO2 > 0, but weakens it in colder climates, ∂λ/∂CO2 < 0Whether feedback CO2‐dependence, ∂λ/∂CO2, is positive or negative primarily depends on the extent of the H2O windowFeedback CO2‐dependence and forcing temperature‐dependence, ∂λ/∂CO2 = −∂F2x/∂Ts, can be important for past or future climates [ABSTRACT FROM AUTHOR]