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Effective Light‐Induced Fluorescent H‐Aggregation of Fluorinated Pyridyl‐Azo Dye via Photoisomerization.
- Source :
-
ChemPhotoChem . May2024, Vol. 8 Issue 5, p1-7. 7p. - Publication Year :
- 2024
-
Abstract
- Here we present the synthesis of a new fluorinated pyridyl‐azo dye and demonstrate an effective way to convert monomer fluorinated pyridyl‐azo dye to H‐aggregated form through UV‐light induced trans‐cis‐trans photoisomerization. And upto a 12 : 88 ratio between monomer : aggregation was achieved through a small pulse of UV irradiation. The H‐aggregation shows a unique high extinction co‐efficient in UV‐visible absorbance and unexpected fluorescence emission with a remarkably large Stokes shift. The solvent DMF and fluorine substituent were found to have a critical role in aggregation. 1H, 19F NMR, and 19F‐DOSY NMR experiments were used to confirm the aggregation and also confirm the absence of π‐π stacking. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 23670932
- Volume :
- 8
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- ChemPhotoChem
- Publication Type :
- Academic Journal
- Accession number :
- 177113487
- Full Text :
- https://doi.org/10.1002/cptc.202300284