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Photocatalytic aerobic α-oxygenation of amides to imides using a highly durable decatungstate tetraphenylphosphonium salt.
- Source :
-
Chemical Communications . 5/7/2024, Vol. 60 Issue 37, p4906-4909. 4p. - Publication Year :
- 2024
-
Abstract
- Decatungstate is a potent photocatalyst for hydrogen atom transfer (HAT) but faces degradation issues when using a typical tetra-n-butylammonium salt. Herein, we employed tetraphenylphosphonium as a countercation to yield a highly durable and efficient HAT photocatalyst, enabling α-oxygenation of amides to their corresponding imides using O2 as an oxidant. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ABSTRACTION reactions
*IMIDES
*SALT
*AMIDES
*TUNGSTATES
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 60
- Issue :
- 37
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 176985146
- Full Text :
- https://doi.org/10.1039/d4cc01016g