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N-nitrosamines in electroplating and printing/dyeing industrial wastewater treatment plants: Removal efficiency, environmental emission, and the influence on drinking water.
- Source :
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Water Research . May2024, Vol. 255, pN.PAG-N.PAG. 1p. - Publication Year :
- 2024
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Abstract
- • Remarkably high NAs were decreased by 33–81 % after industrial WWTPs. • Fe-C electrolysis, ClO 2 oxidation, Fe/Al-based flocculation and activated sludge were effective. • Adsorption, degradation, and precursor deactivation were main removal mechanisms. • Electroplating and printing/dyeing wastewater significantly affect drinking water. • The high concentration diversity of NAs is a major challenge for water treatment. The discharge of industrial wastewater containing high concentrations of N -nitrosamines to the aquatic environment can impair downstream source waters and pose potential risks to human health. However, the transport and fate of N -nitrosamines in typical industrial wastewater treatment plants (IWWTPs) and the influence of these effluents on source water and drinking water are still unclear. This study investigated nine N -nitrosamines in four full-scale electroplating (E-) and printing/dyeing (PD-) IWWTPs, two drinking water treatment plants (DWTPs) in the lower reaches of these IWWTPs, and the corresponding tap water in South China. The total concentrations of N -nitrosamines (∑NAs) were 382–10,600, 480–1920, 494–789, and 27.9–427 ng/L in influents, effluents, source water, and tap water, respectively. The compositions of N -nitrosamine species in different influents varied a lot, while N -nitrosodi-n-butylamine (NDBA) and N -nitrosodimethylamine (NDMA) dominated in most of the effluents, source water, and tap water. More than 70 % N -nitrosamines were removed by wastewater treatment processes used in E-IWWTPs such as ferric-carbon micro-electrolysis (Fe/C-ME), while only about 50 % of N -nitrosamines were removed in PD-IWWTPs due to the use of chlorine reagent or other inefficient conventional processes such as flocculation by cationic amine-based polymers or bio-contact oxidation. Therefore, the mass fluxes of N -nitrosamines discharged from these industrial wastewaters to the environment in the selected two industrial towns were up to 14,700 mg/day. The results based on correlation and principal component analysis significantly demonstrated correlations between E-and PD-effluents and source water and tap water, suggesting that these effluents can serve as sources of N -nitrosamines to local drinking water systems. This study suggests that N -nitrosamines are prevalent in typical IWWTPs, which may infect drinking water systems. The findings of this study provide a basis data for the scientific evaluation of environmental processes of N -nitrosamines. [Display omitted] [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00431354
- Volume :
- 255
- Database :
- Academic Search Index
- Journal :
- Water Research
- Publication Type :
- Academic Journal
- Accession number :
- 176718593
- Full Text :
- https://doi.org/10.1016/j.watres.2024.121537