Enhancing the thermodynamic properties of rare-earth niobates through high-entropy and composite engineering.

High-entropy rare-earth niobates have garnered significant attention in the field of thermal barrier coatings (TBCs) due to their ultra-low thermal conductivity. However, the exceptional thermal properties of fluorite-phase high-entropy rare-earth niobates and the outstanding mechanical properties of monoclinic-phase high-entropy rare-earth niobates cannot be simultaneously harnessed. To address this limitation, this paper investigates and synthesizes five single-phase high-entropy rare-earth niobates: (RE 1/5 Ho 1/5 Er 1/5 Y 1/5 Yb 1/5) 3 NbO 7 (RE = Ce, Sm, Eu, Dy, Lu), and five composite-phase high-entropy rare-earth niobates with a molar ratio of (RE 1/5 Ho 1/5 Er 1/5 Y 1/5 Yb 1/5)NbO 7 : (RE 1/5 Ho 1/5 Er 1/5 Y 1/5 Yb 1/5)NbO 4 = 1:2 (RE = Ce, Sm, Eu, Dy, Lu). The objective is to fabricate niobate coatings that exhibit both outstanding thermal and mechanical properties. The test results reveal that the intrinsic thermal conductivity of the composite-phase samples stands at a mere 1.46 W m−1·K−1 at 1000 °C. Comparatively, the experimental thermal conductivity of the single-phase samples slightly surpasses that of the composite-phase at 1000 °C, registering a minimum of 1.57 W m−1·K−1. Importantly, both values adhere to the TBC standard. The mechanisms behind the low thermal conductivity of the composite-phase and single-phase samples are elucidated by the phonon scattering mechanism and the Cahill model, respectively. Furthermore, the thermal expansion coefficient of the composite-phase samples exceeds that of the single-phase samples overall, and they demonstrate exceptional mechanical properties, offering nearly twice the fracture toughness of the single-phase samples while maintaining high hardness. Experimental evidence shows that composite-phase niobates exhibit enhanced thermodynamic properties compared to single-phase niobates. This work serves as a valuable reference for the utilization of high-entropy rare-earth niobates in the realm of thermal barrier coatings. [ABSTRACT FROM AUTHOR]