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Dioxane promoted photochemical O-alkylation of 1,3-dicarbonyl compounds beyond carbene insertion into C–H and C–C bonds.

Authors :
Zhou, Xinlong
Jiang, Jingjing
Zhang, Min
Wu, Qingqing
Zhu, Keyong
Shi, Dongjie
Hou, Sensen
Zhao, Jingjing
Li, Pan
Source :
Chemical Communications. 4/25/2024, Vol. 60 Issue 32, p4330-4333. 4p.
Publication Year :
2024

Abstract

A photochemical synthesis of enol ethers and furan-3(2H)-ones from 1,3-dicarbonyl compounds and aryl diazoacetates has been developed. Significantly, 1,4-dioxane promoted O-alkylation of various 1,3-dicarbonyl compounds beyond previous carbene insertion into C–H and C–C bonds has been disclosed. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
60
Issue :
32
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
176610331
Full Text :
https://doi.org/10.1039/d4cc00778f