Pattern-based colorimetric sensor array chip for discrimination of Baijiu aromas.

• A pattern-based colorimetric sensor array chip for the identification of typical gas mixtures - Baijiu aroma was constructed. • Nanomaterials can adsorb gas molecules and enhance the reaction of trace gases with the sensor array. • Pattern recognition-based data analysis proved to be perfectly distinguishable between 16 different brands of commercial Baijiu. Gas mixtures are comprised of numerous complex components, making the accurate identification a continuing challenge due to the significant limitations of existing detection methods. Herein, we developed a low-cost and sensitive pattern-based colorimetric sensor array chip for the identification of typical gas mixtures - Baijiu aroma. Specifically, three nanomaterials (AuNPs, MoS 2 and ZIF-8) were prepared to adsorb gas molecules and enhance the reaction of trace gases with sensor arrays. The colorimetric sensor array chip took only 5 min to complete the recognition of Baijiu aromas and effectively avoided recognition errors caused by sommelier olfactory fatigue. Notably, the hierarchical cluster analysis (HCA) revealed no confusion or errors in the results of 80 tests across the five trials involving 16 commercial Baijius. Even fake Baijius with similar ingredients could be easily identified, demonstrating the excellent analytical capabilities of the system in Baijiu identification and its significant potential for quality control of Baijius. [ABSTRACT FROM AUTHOR]