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Switching on emission in Zn(II) coordination complexes by tempering Namido character.
- Source :
-
Chemical Communications . 4/4/2024, Vol. 60 Issue 26, p3515-3518. 4p. - Publication Year :
- 2024
-
Abstract
- A series of four-coordinate zinc(II) complexes is presented in which the amido vs. imino character of a ligated nitrogen donor correlates to the luminescence intensity. DFT analysis points to a distinct mechanism for this trend wherein emission can be switched on by restricting non-radiative decay pathways through the resonance-induced delocalization of amido ligand lone-pairs. [ABSTRACT FROM AUTHOR]
- Subjects :
- *TEMPERING
*LUMINESCENCE
*ZINC
*NITROGEN
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 60
- Issue :
- 26
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 176248851
- Full Text :
- https://doi.org/10.1039/d3cc06227a