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Improved performance of lithium–sulfur battery with a free-standing cobalt-doped vanadium nitride carbon nanofiber interlayer.
- Source :
-
Journal of Electroanalytical Chemistry . Apr2024, Vol. 958, pN.PAG-N.PAG. 1p. - Publication Year :
- 2024
-
Abstract
- An N -doped 3d carbon nanofiber framework embedded with Co-VN (Co-VN/3DNC) was synthesized based on the carbonization of non-woven fabrics. The Co-VN/3DNC interlayer can serve as a physical barrier directly for the shuttle effect alleviating in lithium–sulfur batteries. [Display omitted] • A free-standing Co-VN/DNC interlayer for LSB was synthesized through carbonization method. • Conductive composite interlayer provides additional conductive paths to improve sulfur utilization efficiency. • The Co element could enrich the d orbit electrons of VN, which can enhance the redox performance of the interlayer. • The curved carbon nanotubes can expose active adsorption-catalytic sites, accelerating polysulfide redox kinetics for LSBs. Lithium–sulfur batteries (LSBs) are considered promising devices for next-generation secondary battery owing to their low cost and high energy density. However, the practical application of LSB is hindered by the sluggish redox kinetics of sulfur and the shuttling effect of polysulfide. To address the above problems, cobalt-doped vanadium nitride/three-dimensional carbon nanofiber (Co-VN/3DNC) composites were synthesized based on non-woven fabrics. The Co-VN/3DNC interlayer can serve as a physical barrier directly for the shuttle effect alleviating in LSBs. The introduction of the Co atom can enrich the d-electron number of VN, improving the catalysis of LSBs redox reaction. The growth of curved carbon nanotubes (CNTs) on the surface of the intermediate layer can expose active adsorption-catalytic sites, accelerating polysulfide redox kinetics for LSBs. The electrochemical performance of the LSB is greatly enhanced by the synergistic effect of Co, VN, and 3DNC. The LSB with Co-VN/3DNC interlayer demonstrate a capacity of 1207.7 mAh g−1 at a current density of 0.1C, and retain a specific capacity of 918.2 mAh g−1 even after 250 cycles. This work provides an effective strategy for the intermediate layers design to improve the electrochemical performance of LSBs. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 15726657
- Volume :
- 958
- Database :
- Academic Search Index
- Journal :
- Journal of Electroanalytical Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 176121772
- Full Text :
- https://doi.org/10.1016/j.jelechem.2024.118164