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From a mercury(II) bis(yldiide) complex to actinide yldiides.
- Source :
-
Chemical Communications . 3/21/2024, Vol. 60 Issue 23, p3190-3193. 4p. - Publication Year :
- 2024
-
Abstract
- The bis(yldiide) mercury complex, (L–Hg–L) [L = C(PPh3)P(S)Ph2], is prepared from the corresponding potassium yldiide and used to access the first substituted yldiide actinide complexes [(C5Me5)2An(L)(Cl)] (An = U, Th) via salt metathesis. Compared to previously reported phosphinocarbene complexes, the complexes exhibit long actinide–carbon distances, which can be explained by the strong polarization of the π-electron density toward carbon. [ABSTRACT FROM AUTHOR]
- Subjects :
- *METATHESIS reactions
*MERCURY
*POTASSIUM
*SALT
*DENSITY
*CARBON
*RADIOISOTOPES
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 60
- Issue :
- 23
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 176055100
- Full Text :
- https://doi.org/10.1039/d3cc05553a