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Construction of Snow-Cake Like NiCo2O4 Nanostructures Modified Electrode Material and Its Electrocatalytic Oxidation of Glucose.
- Source :
-
Journal of Inorganic & Organometallic Polymers & Materials . Feb2024, Vol. 34 Issue 2, p712-721. 10p. - Publication Year :
- 2024
-
Abstract
- Transition bimetal oxides are widely used in the field of electrochemical sensing because of their variable valence and bimetallic synergies. In this work, we demonstrate the facile synthesis of snow-cake like NiCo2O4 nanostructures and its application as a working electrode modification material in enzyme-free glucose electrochemical sensing field. In a three-electrode system, the electrocatalytic oxidation activity for glucose of NiCo2O4 nanostructures is tested. The snow-cake like NiCo2O4 nanostructures are endowed with superior electron-transfer capability, large surface area, and abundant intrinsic redox couples of Ni2+/Ni3+ and Co2+/Co3+ ions. The modified electrode exhibits excellent glucose-sensing properties, such as detection of wide range of glucose concentrations with good linearity and high sensitivity of 983 μA mM−1 cm−2 at 0.45 V operating potential. Moreover, the interference from the commonly interfering species such as ascorbic acid (AA), sodium chloride (NaCl) and uric acid (UA) can be effectively avoided. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 15741443
- Volume :
- 34
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- Journal of Inorganic & Organometallic Polymers & Materials
- Publication Type :
- Academic Journal
- Accession number :
- 175966394
- Full Text :
- https://doi.org/10.1007/s10904-023-02855-x