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Construction of 3D structured MXene-h-BN hybrid via thiol-ene click chemistry to enhance thermal and tribological properties of fabric composites.
- Source :
-
Tribology International . May2024, Vol. 193, pN.PAG-N.PAG. 1p. - Publication Year :
- 2024
-
Abstract
- MXene has tremendous potential for enhancing thermal and tribological properties of fabric composites. Yet, its susceptibility to stacking and weak interfacial adhesion in organic matrix impedes practical application. Herein, MXene-h-BN hybrids were successfully achieved utilizing facile thiol-ene click reaction to introduce hexagonal boron nitride onto the surface of MXene to construct unique hierarchical structure. h-BN is grafted onto MXene through covalent bonding, effectively boosting interfacial adhesion and dispersion in the resin matrix. The layered MXene-h-BN possesses good lubrication behavior, and h-BN can increase strength and thermal conductivity of the MXene support skeleton. The results demonstrate that the thermal conductivity, tensile and bonding strength of reinforced fabric composites are elevated by 43.28%, 34.25% and 43.75% compared with pure fabric composites, respectively. Additionally, the wear rate of reinforced fabric composites is significantly decreased by 63.44%. This paper will contribute a novel and prospective reinforcement design strategy for click reaction constructed nano-materials in tribology. • h-BN was efficiently and promptly grafted onto the surface of MXene through the thiol-ene click reaction. • The structure of 3D point plane network was constructed. • The thermal conductivity, tensile and bonding strength of fabric composites are enhanced by 43.28%, 34.25% and 43.75%. • The reinforced fabric composites create robust tribofilm and wear rate is reduced by 30%. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 0301679X
- Volume :
- 193
- Database :
- Academic Search Index
- Journal :
- Tribology International
- Publication Type :
- Academic Journal
- Accession number :
- 175904188
- Full Text :
- https://doi.org/10.1016/j.triboint.2024.109341