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A sharp and selective fluorescence paper-based sensor based on inner filter effect for ratiometric detection of four Sudan dyes in food matrix.
- Source :
-
Food Chemistry . Jun2024, Vol. 444, pN.PAG-N.PAG. 1p. - Publication Year :
- 2024
-
Abstract
- • A ratiometric fluorescent strip is designed based on IFE for detecting Sudan I-IV. • The fluorescent spectrum of Tm@Er has more overlap with the absorption of Sudan I-IV. • Single Tm@Er with core–shell structure provides a more stable ratiometric signal. • UiO-66 improve the adsorption and DMIPs realize the selective detection of Sudan I-IV. • Sensitive and portable application is realized in chilli powder with complex matrix. The addition of Sudan dyes with carcinogenic effects to food threatens human health. Herein, a ratiometric fluorescence strip consisting of core–shell upconversion particles (NaYF 4 :Yb,Tm@NaYF 4 :Yb,Er), metal–organic frameworks and dual-template molecularly imprinted polymers was developed to selectively and sensitively detect four Sudan dyes based on inner filter effect (detection time only takes 8 min). The high adsorption capacity of metal–organic frameworks and the greater overlap between the emission of NaYF 4 :Yb,Tm@NaYF 4 :Yb,Er and the absorbance of four Sudan dyes enable the signal responses to be more sensitive. The limits of detection in chilli powder samples are as low as 29.87 ng/g, 37.55 ng/g, 47.89 ng/g and 51.02 ng/g, with satisfactory recovery (93.32–103.4%) and minor relative standard deviations (≤4.3%). This method broadens the idea for low-cost and portable detection of multiple illegal additives in complex substrates with high selectivity and sensitivity based on one kind of fluorescent strip. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03088146
- Volume :
- 444
- Database :
- Academic Search Index
- Journal :
- Food Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 175873702
- Full Text :
- https://doi.org/10.1016/j.foodchem.2024.138528