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Ring‐Opening Intramolecular Arylation of 1,2‐Disubtituted Epoxides with Tuneable Stereoselectivity.

Authors :
Zhao, Cong‐Cong
Shen, Chaoren
Wang, Bin
Rong, Liangce
Dong, Kaiwu
Source :
European Journal of Organic Chemistry. Mar2024, Vol. 27 Issue 9, p1-8. 8p.
Publication Year :
2024

Abstract

A method of stereodivergent intramolecular ring‐opening arylation of amine‐tethered epoxides to 3,4‐disubstituted tetrahydroquinolines has been developed. The tuneable good stereoselectivity was attained by changing the catalyst from titanocene(III) catalyst to Lewis‐acidic zinc catalyst. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
1434193X
Volume :
27
Issue :
9
Database :
Academic Search Index
Journal :
European Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
175799406
Full Text :
https://doi.org/10.1002/ejoc.202301271