Diversification of NH‐Aryl Sulfoximines through Iridium‐Catalyzed ortho‐ and meta‐Selective C−H Borylation.

Herein, the selective ortho‐ and meta‐C−H bond borylation of NH‐aryl sulfoximines is reported. Regioselectivity is achieved by the choice of commercially available ligands giving fast excess to valuable borylated aryl sulfoximine building blogs. The utility of the borylated products is demonstrated for the formation of C−O, C−C, C−N, C−D, and C−I bonds. [ABSTRACT FROM AUTHOR]