Sustainable energy production from waste paper: A CuMgAlOx-catalyzed approach to alcohol fuels.

[Display omitted] • The alcohol yields achieved were 41.3 wt% and 48.5 wt% from the corrugated box and A4 paper. • Cellulose exhibited the conversion rate of 100 %, with alcohol substances achieving a yield of 71.2 wt% and a selectivity of 89.4 % within 6 h. • The mechanism of cellulose hydrolysis and the catalytic effect of CuMgAlO x were explored. • Multiple techniques were utilized to analyze the alcoholysis pathways and mechanisms of cellulose in waste paper. In an effort to valorize under-exploited cellulose sources like waste paper for sustainable energy production, this study investigates a catalytic process to convert these materials into low-carbon alcohols. We explored the conversion efficiency of various cellulose materials, including corrugated box, A4 paper, and pure cellulose, under the influence of a CuMgAlO x catalyst. Our findings indicate that at 360 °C for 6 h, the conversion rates were substantial, yielding 70.1 % for corrugated box, 85.2 % for A4 paper, and 100 % for cellulose. The respective alcohol selectivities achieved were 54.7 %, 83.0 %, and 89.4 %, with alcohol yields of 41.3 wt%, 48.5 wt%, and 71.2 wt%. Notably, the absence of the catalyst led predominantly to the production of sugars and lipids, whereas the catalytic conditions facilitated the formation of alcohols. The study also examined the effects of temperature and reaction time on cellulose conversion. It was found that a complete conversion was possible at 320 °C within 1 h, with extended temperature and time improving the alcohol yield. The development of a kinetic model for the cellulose conversion process has allowed for accurate predictions of the transformations under varied conditions, which offers a strategic framework for reaction optimization. Furthermore, the role of the CuMgAlO x catalyst was elucidated through the examination of model compounds, demonstrating its capability in converting cellulose intermediates such as sugars, lipids, and ketones into alcohols. This research highlights a potent strategy for the production of high-value, eco-friendly green fuels from readily available paper products and cellulose biomass, marking a significant advancement in chemical engineering and sustainable energy resources. [ABSTRACT FROM AUTHOR]