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Dual-functional urea induced interface reaction enables the improved cycling stability of cation-disordered Li1.2Ti0.4Mn0.4O2 cathode.
- Source :
-
Journal of Solid State Electrochemistry . Aug2024, Vol. 28 Issue 8, p2741-2752. 12p. - Publication Year :
- 2024
-
Abstract
- Cation-disordered rocksalt (DRX) oxides show promise as lithium-ion battery cathodes due to their high theoretical capacity derived from anionic redox. However, the challenges of poor anionic redox reversibility, causing oxygen loss and voltage hysteresis, lead to rapid capacity decay. This study employs a dual-functional urea treatment on Li1.2Ti0.4Mn0.4O2 DRX cathodes, generating oxygen vacancies in the subsurface and a protective carbon nitride layer on the surface through interface reactions. Characterization via X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy confirms these alterations. The presence of oxygen vacancies reduces the average Mn valence, increasing the capacity contributed by Mn and enhancing the reversibility of anionic oxygen redox, thus curbing oxygen loss. Additionally, the carbon nitride layer curtails the parasitic reaction between active oxygen species and the electrolyte. Urea-treated Li1.2Ti0.4Mn0.4O2 exhibits enhanced electrochemical performance, retaining a higher capacity (151 mAh⋅g−1, 80.3% of capacity retention) after 50 cycles compared to neat Li1.2Ti0.4Mn0.4O2 (117 mAh⋅g−1, 64.6% retention). Furthermore, the treatment improves lithium-ion diffusion and rate capability. This dual-functional urea approach presents a promising strategy for enhancing DRX cathode materials and advancing high-performance lithium-ion batteries. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14328488
- Volume :
- 28
- Issue :
- 8
- Database :
- Academic Search Index
- Journal :
- Journal of Solid State Electrochemistry
- Publication Type :
- Academic Journal
- Accession number :
- 178416639
- Full Text :
- https://doi.org/10.1007/s10008-024-05831-8