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Semi-fluorinated (6F) polyaryl ethers and polyphenylenes via interfacial electrophilic condensation polymerization with hexafluoroacetone hydrate.
- Source :
-
Polymer . Feb2024, Vol. 293, pN.PAG-N.PAG. 1p. - Publication Year :
- 2024
-
Abstract
- A series of semi-fluorinated polymers were obtained by Friedel-Crafts polymerization of hexafluoroacetone trihydrate (HFAH) with a variety of activated and non-activated aromatic monomers. Interfacial (water/dichloroethane) electrophilic aromatic substitution (EAS) polymerizations were carried out with trifluoromethanesulfonic anhydride (Tf 2 O) and Aliquat® 336 as phase transfer catalyst. This versatile and straightforward method achieved the synthesis of moderate to high molecular weight (12.0–29.6 kDa) polyaryl ethers and polyphenylenes with 1,1,1,3,3,3-hexafluoroisopropylene (6F) main chain linkages. Predominantly amorphous film-forming materials were obtained with low branching, high solubilities in common organic solvents, thermo-oxidative stabilities up to 500 °C, and glass transitions (T g) ranging from 157 to 250 °C. The optical and dielectric properties of these materials were also studied from which high visible region transmittance and low dielectric constant values comparable with commercial materials were found. [Display omitted] • Semi-fluorinated polyaryl ethers and polyarylenes from inexpensive aromatic monomers. • Mild conditions for direct EAS polymerization of hexafluoroacetone with aromatic monomers. • Soluble polymers with high thermal oxidative stability and high glass transition temperature. • Methodology to prepare random or segmented EAS copolymers with unique properties. • Amorphous thermoplastics with good optical transparency and low dielectric constant. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00323861
- Volume :
- 293
- Database :
- Academic Search Index
- Journal :
- Polymer
- Publication Type :
- Academic Journal
- Accession number :
- 174917011
- Full Text :
- https://doi.org/10.1016/j.polymer.2023.126642