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A library of benzimidazole based amide and urea derivatives as supramolecular gelators – A comparative study.
- Source :
-
Journal of Molecular Liquids . Feb2024, Vol. 395, pN.PAG-N.PAG. 1p. - Publication Year :
- 2024
-
Abstract
- [Display omitted] • Synthesis, characterization and applications of novel bisamide and bisurea functionalized benzimidazole compounds. • Probing the mechanism of gelation in both series of compounds using various physicochemical techniques. • Role of bisamide and bisurea functional groups on gelation behaviour is explored. • Bisamide and bisurea compounds displayed highly selective detection of mercury ion in solution. We present a set of alkyl chain functionalized benzimidazole based compounds containing amide and urea functional groups which were screened for their gelation behaviour. Both the sets bear similar molecular scaffolds, making them an excellent tool for determining the role of the supramolecular interactions involved in the gelation process. All the compounds were characterised using physico-chemical techniques like NMR and FT-IR. The gels were subjected to small angle neutron scattering studies (SANS), rheological studies, SEM and FT-IR. In order to rationalize the gelation behaviour, solvent parameter studies were conducted. The results show a dependence on refractive index of solvent, polarizability and dispersion interactions. The respective orientation of amide and conformation in urea based compounds were explored and studied using computational calculations and their corresponding effect on the resulting supramolecular superstructures was scrutinized. The compounds were also explored to act as chemosensor for selective detection of mercuric ions with exceptionally low LOD (limit of detection) values. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01677322
- Volume :
- 395
- Database :
- Academic Search Index
- Journal :
- Journal of Molecular Liquids
- Publication Type :
- Academic Journal
- Accession number :
- 174914437
- Full Text :
- https://doi.org/10.1016/j.molliq.2023.123858