Bayesian optimization of periodic multilayered slabs for passive absorptivity control.

• Functional multilayer with VO 2 was proposed for passive emissivity control. • Suitable geometric parameters were determined using Bayesian optimization. • Bayesian optimization saved computational cost less than a few percent. • Radiative cooling was promoted with two isolated metallic VO 2 slabs. • Insulating VO 2 suppressed radiative cooling performance at cold environment. A vanadium dioxide (VO 2) film grown on a titanium oxide crystal shows a metal–insulator transition at room temperature with drastically changed optical properties. A multilayered slab with a sub-micron scale VO 2 film was proposed to utilize its unique properties for passive intensity control of sunlight absorption and radiative cooling. Its optimal geometries were numerically explored using the Bayesian optimization (BO) method. BO was applied for three types of multilayered slabs, those having one, two, or three isolated slabs of different widths. For each type of multilayered slab, BO could optimize geometric variables with practical calculation times considering the total number of possible combinations of variables, which is subsequently referred to as the total number of candidates. Optimization results revealed that two isolated slabs had the most suitable spectral absorptivity in both hot and cold environments. The infrared absorptivity of the double slab was kept low in cold conditions to suppress radiative cooling. However, the double slab exhibited good radiative cooling performance under hot conditions. Electromagnetic energy density surrounding the slab illustrated that metallic VO 2 and gold placed in a parallel manner excited the coupled mode of surface plasmon polaritons to enhance absorptivity. Radiative cooling faded for the triple slab because each slab could couple with radiation propagating only across a portion of the cross-sectional area. Through three BO trials, improvement of the VO 2 visible reflectivity was recognized as a future issue for further development of passive sunlight absorption control. [ABSTRACT FROM AUTHOR]