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Novel and efficient Bi-doped CoTe nano-solar evaporators embedded on leno weave cotton gauze for efficient solar-driven desalination.

Authors :
Tabassum, Javeria
Baig, Nadeem
Sohail, Manzar
Nafady, Ayman
Shah, Syed Shoaib Ahmad
Ul‐Hamid, Anwar
Tsiakaras, Panagiotis
Source :
Journal of Colloid & Interface Science. Mar2024, Vol. 658, p758-771. 14p.
Publication Year :
2024

Abstract

[Display omitted] • Bi-doping enhanced the surface plasmonic effect of CoTe nanoparticles. • The optimization of morphology enhanced surface plasmonic effect. • The surface plasmonic effect can be translated into heat for desalination. • 5 % Bi-doping (Bi/CoTe@CG) exhibited an excellent water flux of 2.38 kg m−2 h−1. • The Bi/CoTe@CG showed a solar efficiency of 96.7 %. Solar-driven desalination is considered an alternative to the conventional desalination due to its nearly zero carbon footprint and ease of operating in remote areas. Water can be purified wherever sunlight is available, providing a viable solution to water shortage. Metal chalcogenide-based materials are revolutionary for solar evaporators due to their excellent photothermal conversion efficiency, facile synthesis methods, stability, and low cost. Herein we present a prototype Bi-doped CoTe nano-solar evaporator embedded on leno weave cotton gauze (Bi/CoTe@CG) using the sonication process. The nano-solar evaporator was synthesized using a simple hydrothermal approach to provide an opportunity to scale up. The as designed solar evaporator consisting of 5 % Bi/CoTe@CG showed an excellent water flux of 2.38 kg m−2 h−1 upon one sun radiation (1 kW m−2), considered among the highest literature-reported values. The introduced solar evaporator showed excellent solar efficiency of 96.7 %, good stability, and reusability for five cycles of one hour. The best doping ratio of Bi in CoTe was obtained as Bi 0.5 Co 9.5 Te with a contact angle of 11.9° in powder form. The hydrophilic nature of the designed solar-evaporator increased the water interaction with the embedded nano-solar evaporator, which helps the transfer of the heat to nearby water molecules, break their hydrogen bonding and increase the evaporation rate. The ion concentration, of the desalinated pure water collected using Bi/CoTe@CG, decreased by many orders of magnitude and it is far below the limit of WHO standards for Na+ and K+. Thus, a self-floating Bi-doped CoTe nano-solar evaporator deposited on cotton gauze (CG) is an excellent solar evaporator for seawater desalination. The proposed solar evaporator is another step towards introducing environmentally friendly desalination methods. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00219797
Volume :
658
Database :
Academic Search Index
Journal :
Journal of Colloid & Interface Science
Publication Type :
Academic Journal
Accession number :
174666195
Full Text :
https://doi.org/10.1016/j.jcis.2023.12.089