Influence of cation concentration and valence on the structure and texture of spray-dried supraparticles from colloidal silica dispersions.

The addition of salt has a pronounced impact on the stability of nanoparticles. By varying the salt types and concentrations, the structure of spray-dried supraparticles from binary SiO 2 nanoparticle dispersions can be tuned from core-shell to Janus-like and well-mixed. The surface roughness and porosity are modified accordingly. In summary, this study presents a feasible way to synthesize particles with different supraparticular structures by elucidating the role of ionic strength on different sizes of nanoparticles. [Display omitted] The structure and texture of supraparticles determine their properties and performance, thus playing a critical role in research studies as well as industrial applications. The addition of salts is a well-known strategy to manipulate the colloidal stability of nanoparticles. In this study, this approach is used to tune the structure of spray-dried supraparticles. Three different salts (NaCl, CaCl 2 , and AlCl 3) were added to binary silica (SiO 2) nanoparticle dispersions (of 40 and 400 nm in size) to change their colloidal stability by lowering the electrostatic repulsion or enhancing the cation bridging. Dependent on the cation valence of the added salt and the nanoparticle size, the critical salt concentration, which yields nanoparticle agglomeration, is reached at different salt amounts. This phenomenon is exploited to tune the final structure of supraparticles - obtained by spray-drying binary dispersions - from core-shell to Janus-like to well-mixed structures. This consequently also tunes textural properties, like surface roughness and the pore system of the obtained supraparticles. Our results provide insights for controlling the structure of spray-dried supraparticles by manipulating the stability of binary nanoparticle dispersions, and they establish a framework for composite particle design. [ABSTRACT FROM AUTHOR]