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Anti-electrostatic cation⋯π-hole and cation⋯lp-hole interactions are stabilized via collective interactions.
- Source :
-
Chemical Communications . 1/14/2024, Vol. 60 Issue 4, p400-403. 4p. - Publication Year :
- 2024
-
Abstract
- Collective interactions are a novel type of bond between metals and AX3 fragments with an electropositive central atom, A, and electronegative X substituents. Here, using electrostatic potential maps and state-of-the-art bonding analysis tools we have shown that collective interactions are anti-electrostatic cation⋯π-Hole or cation⋯lp-Hole interactions. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ELECTRIC potential
*METAL bonding
*CATIONS
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 60
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 174600594
- Full Text :
- https://doi.org/10.1039/d3cc05451a