Back to Search
Start Over
Hydrothermal synthesis and characterization of a new inorganic–organic hybrid cadmium phosphate Cd(phen)(H2PO4)2⋅H2O
- Source :
-
Solid State Sciences . Mar2005, Vol. 7 Issue 3, p319-323. 5p. - Publication Year :
- 2005
-
Abstract
- Abstract: A new inorganic–organic hybrid solid, Cd(phen)(H2PO4)2⋅H2O (phen=1,10-phenanthroline), has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, FTIR, elemental analysis, ICP analysis, powder X-ray diffraction and fluorescent spectrum. The compound crystallizes in the triclinic system, space group P-1 (No. 2), , , , , , , , . The structure is built from strictly alternating CdO4N2 octahedra and H2PO4 tetrahedra through their vertices, forming an infinite ladder-like architecture. This compound shows intense photoluminescence upon photoexcitation at 358 nm. [Copyright &y& Elsevier]
- Subjects :
- *CADMIUM compounds
*SOLIDS
*X-ray diffraction
*CRYSTALS
*SPECTRUM analysis
Subjects
Details
- Language :
- English
- ISSN :
- 12932558
- Volume :
- 7
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Solid State Sciences
- Publication Type :
- Academic Journal
- Accession number :
- 17453061
- Full Text :
- https://doi.org/10.1016/j.solidstatesciences.2004.10.043