Influence of methane seep activities and sea-level changes on elemental and isotopic compositions and abundance of carbonates in sediments of the Okinawa Trough since the last glacial period.

[Display omitted] • Carbonates in sediments of the Okinawa Trough are biogenic and authigenic in origin. • Authigenic carbonate in sediments of the Okinawa Trough is mainly high-Mg calcite. • The negative carbon isotope values reflect the origin of authigenic carbonate from AOM. • Biogenic carbonate contents were low (high) during the glacial (interglacial) period. The elemental and isotopic compositions and abundance of carbonates in marine sediments are used to reconstruct ancient climate and ocean conditions. These carbonates usually include biogenic and authigenic carbonates in origin, which are controlled by sedimentary and diagenetic processes, respectively. However, the specific mechanisms involved in controlling the origin of biogenic and authigenic carbonates are still unclear. To address this knowledge gap, we analyzed core CSHC-4 sediment from the Okinawa Trough to examine the elemental and isotopic compositions of carbonates and their relationship to methane seepage and sea-level changes. Our results indicate that high-Mg calcite is the dominant authigenic carbonate, indicating moderate methane seep intensity. Negative carbon isotope values as low as −4.06‰ V-PDB of the bulk sediments deposited in the glacial period suggest a connection between the formation of authigenic carbonates and methane seepage. Negative oxygen isotope values as low as −2.6‰ V-PDB may be attributed to the input of 18O-depleted fluids influenced by gas hydrate formation. Biogenic carbonates contribute the majority (96.3%) of the total carbonate contents in sediments. Biogenic carbonate contents are lower during glacial periods and higher during interglacial periods. The reduced carbonate content during glacial periods may be due to lower export productivity influenced by the deepening of North Pacific Intermediate Water, as well as terrestrial inputs and anoxic conditions during low sea level periods. Our findings highlight the importance of considering both biogenic and authigenic carbonates when reconstructing paleoclimate and paleoceanography based on their geochemical characteristics. [ABSTRACT FROM AUTHOR]