Newly design and synthesis of Ni–Ir–Ru-doped mesoporous silica open-frameworks for admirable electrochemical water-oxidation application.

As traditional non-renewable energy sources become scarcer, researchers are exploring effective strategies for producing sustainable and renewable energy. Oxygen evolution reaction through electrocatalytic water splitting (EC-OER) on the surface of a semiconductor has drawn much more attention in the worldwide as it has the principal role towards the several kind of energy applications viz. fuel cell, metal-ion rechargeable batteries and water oxidation. It is extremely difficult to develop eco-friendly, plentiful, and cost-effective nanomaterials as catalysts in order to achieve high efficiency of hydrogen production through water splitting. Furthermore, hierarchical nanostructures will become more valuable in future energy conversion applications due to their excellent physicochemical properties. Herein, we have synthesized total six different kinds of multi-metal-doped porous silica nanomaterials by utilizing the combination of nickel, iridium, and ruthenium metal slats in order to explore them as potential catalysts for electrochemical water oxidation process. We present a simple strategy to synthesize multi-metal-doped silica materials with spherical morphology, deploying a cation surfactant template (CTAB) as a structure directing agent in water-ethanol solvent mixtures. These materials are thoroughly characterized with the help of powder X-ray diffraction (PXRD), UV–Vis, FT-IR, X-ray photoelectron spectroscopy (XPS), high resolution transmission electron microscopy (HR-TEM), field emission scanning electron microscopy (FE-SEM), nitrogen-sorption isotherm, thermogravimetric (TGA) analysis. The particles are 550–600 nm in size with a fine-looking spherical morphology and surface area in the range of 111–419 m2/g. Among all of these metal-silica, Ni–Ir–Ru-doped mesoporous silica particles (NIRS) exhibit excellent electrocatalytic activity towards oxygen evolution reaction (100 mA/cm2 current density@0.5V) with long-term durability up to 10 h, and the Tafel slope is also very low (∼68 mV/dec) in 1 M KOH medium. The excellent electrical conductivity of Ni–Ir–Ru-doped silica makes it a superior electrocatalyst due to its spherical morphology, synergistic effects of the multi metallic components, and its hierarchical nanoporous structure. [Display omitted] • A facile method for multi-metal-doped mesoporous silica was developed. • The particle sizes were 550–600 nm and surface area were up to 419 m2/g. • Multi-metal-doped mesoporous silica particles were spherical particles. • NIRS generated 100 mA/cm2 and current density@0.5V during OER in pH=14. • NIRS exhibited high durability up to 10 h with Tafel slope of 68 mV/dec in pH=14. [ABSTRACT FROM AUTHOR]