Flexible NiFeP@filter paper electrode for alkaline overall water electrosplitting.

The large-scale development of flexible electrode is urgently needed for water electrosplitting. Herein, the common and low-cost filter paper (FP) is utilized as the substrate to adjust the flexible property of the catalytic electrode. Through an electroless plating method, the NiFeP alloys were deposited onto the filter paper, which acted as the flexible and self-supported electrode for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). The resultant NiFeP@FPs require low overpotentials of 158 mV for HER and 282 mV for OER to deliver a current density of 10 mA cm−2, and exhibit a good stability of 30 h in 1 M KOH. The synergistic effect of Fe–Ni sites regulates electron structure and boosts the catalytic activity. Benefited from good hydrophilicity and interlaced fiber structure of filter paper, electrolyte penetration and electron transfer in the sample are promoted. The assembled two-electrode electrolyzer only requires 1.814 V to achieve 100 mA cm−2 for overall water splitting and shows excellent stability. This work provides a new strategy for the development of flexible and efficient electrodes for water splitting, which advances the development of wearable electronic devices. [Display omitted] • The flexible filter paper-based electrode was successfully synthesized. • The good hydrophilicity and porous structure facilitated electrolyte permeation. • The sample required low overpotentials of 158 mV for HER and 282 mV for OER. • The two-electrode electrolyzer provided 100 mA cm−2 at a low voltage of 1.814 V. [ABSTRACT FROM AUTHOR]