Back to Search
Start Over
New ruthenium/phosphino carbazole systems for selective preparation of alcohols under hydroformylation conditions.
- Source :
-
Journal of Organometallic Chemistry . Jan2024, Vol. 1004, pN.PAG-N.PAG. 1p. - Publication Year :
- 2024
-
Abstract
- • P/N-H ligand facilitates Ru to exhibit efficient hydrogenation under CO. • The NH effect of ligands promote the hydrogenation process. • Co/Ru- L1 system smoothly achieves alcohol production under hydroformylation conditions. Efficient hydrogenation of aldehydes is highly desirable in hydroformylation process to obtain alcohol products. This work developed carbazole-derived phosphine ligands for efficient Ru-catalyzed hydrogenation of aldehydes in the presence of carbon monoxide. Up to 99 % yields of alcohols were obtained in the presence of high-pressure CO at 130 ℃. The results of different ligands revealed the crucial role of N H moiety on carbazole in promoting the catalytic hydrogenation. It was applied to the Co/Ru-catalyzed hydroformylation process, resulting in the production of long-chain alcohols with excellent yields. [Display omitted] [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 0022328X
- Volume :
- 1004
- Database :
- Academic Search Index
- Journal :
- Journal of Organometallic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 174297142
- Full Text :
- https://doi.org/10.1016/j.jorganchem.2023.122927