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Visible‐Light‐Promoted Palladium‐Catalyzed Cross‐Coupling of Iodocarboranes with Disulfides and Phenylselenyl Chloride†.
- Source :
-
Chinese Journal of Chemistry . Jan2024, Vol. 42 Issue 2, p129-134. 6p. - Publication Year :
- 2024
-
Abstract
- Comprehensive Summary: This work describes a general method for the synthesis of a series of sulfenylated and selenylated carboranes at room temperature using readily available iodocarboranes as starting materials via boron‐centered carboranyl radicals. Such hypervalent boron radicals are generated by a visible‐light‐promoted Pd(0)/Pd(I) pathway. They are useful intermediates and can be trapped by disulfides and phenylselenyl chloride for the convenient construction of B—S/Se bonds. [ABSTRACT FROM AUTHOR]
- Subjects :
- *CARBORANES
*BORON
*RADICALS
*CHLORIDES
*PHOTOCATALYSIS
Subjects
Details
- Language :
- English
- ISSN :
- 1001604X
- Volume :
- 42
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- Chinese Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 174271597
- Full Text :
- https://doi.org/10.1002/cjoc.202300481