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Contracted description of driven degenerate multilevel quantum systems.

Authors :
Xu, Xiangyu
Sun, Kewei
Gelin, Maxim F.
Zhao, Yang
Source :
Journal of Chemical Physics. 12/14/2023, Vol. 159 Issue 22, p1-10. 10p.
Publication Year :
2023

Abstract

We formulate a contraction theorem that maps quantum dynamics of a multilevel degenerate system (DS) driven by a time-dependent external field to the dynamics of the corresponding contracted non-degenerate system (CNS) of lower dimension, provided transitions between each pair of degenerate levels in the DS have identical transition dipole moments. The theorem is valid for an external field of any strength and shape, with and without rotating wave approximation in the system–field interaction. It establishes explicit relations between DS and CNS observables, significantly simplifies numerical calculations, and clarifies physical origins of the field-induced DS dynamics. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00219606
Volume :
159
Issue :
22
Database :
Academic Search Index
Journal :
Journal of Chemical Physics
Publication Type :
Academic Journal
Accession number :
174233638
Full Text :
https://doi.org/10.1063/5.0178460