Comment on "Phosphine in the Venusian Atmosphere: A Strict Upper Limit From SOFIA GREAT Observations" by Cordiner et al.

Searches for phosphine in Venus' atmosphere have sparked a debate. Cordiner et al. (2022, https://doi.org/10.1029/2022gl101055) analyze spectra from the Stratospheric Observatory For Infrared Astronomy (SOFIA) and infer <0.8 ppb of PH3. We noticed that some spectral artifacts arose from non‐essential calibration‐load signals. By‐passing these signals allows simpler post‐processing and a 5.7σ candidate detection, suggesting ∼3 ppb of PH3 above the clouds. Compiling six phosphine results hints at an inverted abundance trend: decreasing above the clouds but rising again in the mesosphere from some unexplained source. However, no such extra source is needed if phosphine is undergoing destruction by sunlight (photolysis), to a similar degree as on Earth. Low phosphine values/limits are found where the viewed part of the super‐rotating Venusian atmosphere had passed through sunlight, while high values are from views moving into sunlight. We suggest Venusian phosphine is indeed present, and so merits further work on models of its origins. Plain Language Summary: Cordiner et al. (2022, https://doi.org/10.1029/2022gl101055) find no phosphine in Venus' atmosphere, using the airborne SOFIA telescope. By‐passing some instrumental effects, we extract a detection with 5.7σ‐confidence from the same data. We can resolve the tension between high and low PH3 abundance values by noticing that the former are from "mornings" in Venus' atmosphere and the latter from "evenings." Sunlight reduces the amount of phosphine in Earth's atmosphere by an order of magnitude, so similarly on Venus, we might expect lower abundances in data taken when the part of the atmosphere observed has passed through sunlight. If the six available data sets can be reconciled in this way, further modeling of possible sources of PH3 (e.g., volcanic, disequilibrium chemistry, extant life) seem worthwhile. Key Points: We recover Venusian phosphine in SOFIA spectra by reducing contaminating signals; the PH3 abundance is ∼3 part‐per billion (ppb)Six recoveries/limits show PH3 depleting between clouds and mesosphere, which would require an unknown re‐formation process or extra sourceRecoveries and upper limits can instead be reconciled by PH3 photolysis, as high/low abundances correspond to Venusian mornings/evenings [ABSTRACT FROM AUTHOR]