Biomass steam gasification for hydrogen-rich syngas production over fly ash-based catalyst pretreated by coupling of washing and calcination.

Biomass gasification to produce syngas is promising, but the limited hydrogen content of the syngas restricts its potential applications. This study proposed an efficient thermochemical approach that used cost-effective fly ash pretreated with washing and calcination (WCFA) as a catalyst to enhance hydrogen-rich syngas production from biomass steam gasification. Catalyst characterizations indicated that washing removed most chloride salts in raw fly ash by dissolution, and subsequent calcination decomposed Ca-containing compounds into CaO, resulting in smaller catalyst grains, more developed pore structure, and greater capability and reaction rate of CO 2 sorption. With WCFA, the H 2 release during gasification was prolonged by ∼10 min and its release peak increased by over 1.5 times, compared to no catalyst. Consequently, the cold gas efficiency, syngas yield, and H 2 /CO ratio increased from 53%, 792 mL/g biomass , and 0.39 for no catalyst to 72%, 1132 mL/g biomass , and 1.05 for WCFA. The WCFA catalyst calcined at 800 °C for 60 min was optimal for H 2 formation, due to its enriched CaO composition and improved porosity, which effectively catalyzed volatiles cracking/reforming and absorbed CO 2 to lead the chemical equilibrium of water gas shift reaction move foward. [Display omitted] • Fly ash pretreated by coupling of washing and calcination (WCFA) showed enriched CaO and improved porosity. • WCFA enhanced the H 2 release. • WCFA increased cold gas efficiency, syngas yield and H 2 /CO ratio by 1.36, 1.43 and 2.69 folds. • WCFA catalyzed volatile cracking/reforming and promoted water gas shift reaction by CO 2 sorption. [ABSTRACT FROM AUTHOR]