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A zinc coordination compound showing green photoluminescence.
- Source :
-
Zeitschrift für Naturforschung B: A Journal of Chemical Sciences . Nov2023, Vol. 78 Issue 11/12, p543-547. 5p. - Publication Year :
- 2023
-
Abstract
- A novel three-dimensional coordination compound has been solvothermally synthesized based on a tetracarboxylate ligand H4L (H4L = 1,3,6,8-tetrakis(4-carboxylphenyl)pyrene), Zn2L(H2O)2·2DEF (1) (DEF = N,N′-diethylformamide). Each Zn ion is coordinated by four carboxylate oxygen atoms from four L4− ligands and one oxygen atom from a water molecule to provide a distorted square-pyramidal geometry. Pairs of adjacent Zn cations are bridged by four carboxylate groups of four different L4− ligands to generate a paddle-wheel [Zn2(COO)4(H2O)2] secondary building unit (SBU). Each SUB is further linked to four L4− ligands to give a three-dimensional framework with cds-type (CdSO4-type) topology. The crystal structure has been determined via single-crystal X-ray diffraction, and the compound was characterized by elemental and thermal analysis, infrared spectroscopy, powder X-ray diffraction, and solid-state photoluminescence measurements. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09320776
- Volume :
- 78
- Issue :
- 11/12
- Database :
- Academic Search Index
- Journal :
- Zeitschrift für Naturforschung B: A Journal of Chemical Sciences
- Publication Type :
- Academic Journal
- Accession number :
- 173893369
- Full Text :
- https://doi.org/10.1515/znb-2023-0063