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Iron‐catalyzed Hydrosilylation of Secondary Carboxamides: Chemoselective Access to Aldimines.
- Source :
-
ChemCatChem . 11/22/2023, Vol. 15 Issue 22, p1-6. 6p. - Publication Year :
- 2023
-
Abstract
- This contribution described the chemoselective reduction of secondary carboxamides to aldimines. To perform such challenging transformation, we reported a catalyzed hydrosilylation using Fe(CO)4(IMes) [IMes=1,3‐bis (2,4,6‐trimethylphenyl) imidazol‐2‐ylidene] as the catalyst, diphenylsilane as the reductant under UV irradiation (350 nm) at room temperature for 16 h. Aldimines were then obtained, after a basic quench, in 32–83 % isolated yields. This transformation was unprecedented at iron. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ALDIMINES
*HYDROSILYLATION
*CARBOXAMIDES
*IRON
*CATALYSTS
Subjects
Details
- Language :
- English
- ISSN :
- 18673880
- Volume :
- 15
- Issue :
- 22
- Database :
- Academic Search Index
- Journal :
- ChemCatChem
- Publication Type :
- Academic Journal
- Accession number :
- 173849273
- Full Text :
- https://doi.org/10.1002/cctc.202300963