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Chemoselective light‐induced reactivity of β‐enaminones.
- Source :
-
Photochemistry & Photobiology . Jul2024, Vol. 100 Issue 4, p1068-1077. 10p. - Publication Year :
- 2024
-
Abstract
- The irradiation of β‐enaminones, generated in situ from cyclic 1,3‐diketones and activated alkenes leads to polyheterocyclic skeletons. The photoproduct chemoselectivity depends on the type of cyclic 1,3‐diketones employed viz., 2‐acetylcyclopentanone and 2‐acetylcyclohexanone. The observed chemoselectivity was rationalized based on the Dieckmann‐Kon rule. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ALKENES
*SKELETON
*IRRADIATION
*PHOTOCHEMISTRY
*CHEMOSELECTIVITY
*PHOTORECEPTORS
Subjects
Details
- Language :
- English
- ISSN :
- 00318655
- Volume :
- 100
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- Photochemistry & Photobiology
- Publication Type :
- Academic Journal
- Accession number :
- 178647309
- Full Text :
- https://doi.org/10.1111/php.13889