Dimension Tuning of All‐Inorganic Ag‐Based Metal Halides by Solvent Engineering.

Dimension growth of metal halides is important for its properties and applications. However, such dimension control of the metal halides is rarely reported in the literature and the growth mechanism is not clear yet. A minute difference of solvent properties can tremendously alter the process of nucleation and growth of crystals. Herein, an intriguing phenomenon of dimension tuning for Ag‐based metal halides is reported. The 1D Cs2AgCl3 crystals can be obtained in pure DMF while the 2D CsAgCl2 crystals are obtained in pure DMSO. Both exhibit bright yellow emission, which are derived from self‐trapping excitons (STEs). The photoluminescence quantum yield (PLQY) of Cs2AgCl3 (1D) and CsAgCl2 (2D) are 28.46 % and 20.61 %, respectively. In order to understand the mechanism of the dimension change, additional solvents (N,N‐dimethylacetamide, DMAC, 1,3‐Dimethyl‐Tetrahydropyrimidin‐2(1H)‐one, DMPU) are also selected to process the precursor for crystal growth. By comparing the functional group, dielectric constant, and donor number among the four solvents, we find the donor number plays the predominant role in nucleation process for Cs2AgCl3 and CsAgCl2. This research reveals the relationship between coordination ability of the solvent and the dimension of metal halides. [ABSTRACT FROM AUTHOR]