Pyrolyzed POMs@ZIF-67 Exhibiting High Performance as Direct Glucose Fuel Cell Anode Catalysts.

Polyoxometalates (POMs) are three-dimensional materials with unique, exceptional physical and chemical characteristics. The performance of POM-derived materials is anticipated to be enhanced by the combination of POM and metal–organic frameworks (MOFs) due to the high surface areas of MOF materials. In this study, three kinds of T-POMs@ZIF-67 (T-PMo@ZIF-67, T-SiW@ZIF-67, and T-PW@ZIF-67) were prepared by doping a cobalt-based MOF (ZIF-67) with three POMs (phosphomolybdic acid, silicotungstic acid, and phosphotungstic acid). The results show that the power density of the T-PMo@ZIF-67 catalyst anode is 3.08 times that of the blank control anode and 1.34 times that of the CoMoO4 catalyst. These findings suggest that the synthesis of MOF derivatives by doping MOFs with POM will have significant potential for use in the fuel cell industry. [ABSTRACT FROM AUTHOR]