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Aminoalcohol derivatives by nickel-catalyzed enantioselective coupling of imines and dienol ethers.
- Source :
-
Chemical Communications . 10/28/2023, Vol. 59 Issue 84, p12613-12616. 4p. - Publication Year :
- 2023
-
Abstract
- The reductive coupling of dienol ethers with N-tosylimines catalyzed by Ni(0) in the presence of a VAPOL-derived phosphoramidite ligand follows an unprecedented regiochemical course; it furnishes syn-configured 1,2-aminoalcohol derivatives in good chemical yields with up to 94% ee. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ETHERS
*CHEMICAL yield
*CHEMICAL derivatives
*AMINATION
*IMINES
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 59
- Issue :
- 84
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 173105050
- Full Text :
- https://doi.org/10.1039/d3cc04582j