Back to Search Start Over

A hydrazine-based unsymmetrical bis-imine-Schiff base as a chemosensor for turn-off fluorescence and naked-eye detection of Cu2+ ion: Application in aqueous media using test strips.

Authors :
Goswami, Nilotpal
Priya Gogoi, Himadri
Barman, Pranjit
Source :
Journal of Photochemistry & Photobiology A: Chemistry. Jan2024, Vol. 446, pN.PAG-N.PAG. 1p.
Publication Year :
2024

Abstract

[Display omitted] • A hydrazine-based unsymmetrical bis-Schiff base (L 1) was synthesized. • L 1 acts as a highly selective and reversible chemosensor for naked-eye detection of Cu2+ ions. • L 1 shows "turn-off" fluorescence in presence of Cu2+ ions. • L 1 coated test strips were capable of rapid detection of Cu2+ ions in aqueous medium. • The Limit of Detection found was below the recommended limit as per WHO guidelines. A new hydrazine-based unsymmetrical bis-imine-Schiff base 1-((((5-bromothiophen-2-yl)methylene)hydrazono)methyl)naphthalen-2-ol (L 1) was synthesized and characterized with FT-IR, 1H NMR, 13C NMR, UV–visible spectroscopy, ESI-MS, and elemental analysis. The solution of L 1 in dichloromethane/methanol (9.8:0.2,v/v) mixture shows a rapid change in color from yellow to yellowish brown in the presence of Cu2+ ions. In addition, L 1 displays "turn-off" fluorescence preferentially for Cu2+ ions which was attributed to the Chelation Enhanced Quenching (CHEQ) effect caused due to the reversible binding of L 1 to paramagnetic Cu2+ in a 2:1 stoichiometric ratio. No interference was caused in the sensing process by other metal ions such as Ag+, Na+, Ni2+, Co2+, Hg2+, Cr3+ Ba2+, Ca2+, Cd2+, Pb2+, Sn2+, Zn2+, Fe3+, Al3+, K+, and Sr2+. The limit of detection was determined to be 2.809 µM. Furthermore, the test strips coated with L 1 show a change in color from pale yellow to brownish-yellow in the presence of Cu2+ions in the aqueous medium, and the limit of visual detection was found to be 15 µM, which is well under the maximum recommended limit (31.5 µM) of Cu2+ for drinking water as per WHO guidelines. These observations establish L 1 as an efficient reversible chemosensor for sensing Cu2+ in both aqueous and non-aqueous media with high sensitivity and selectivity. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
10106030
Volume :
446
Database :
Academic Search Index
Journal :
Journal of Photochemistry & Photobiology A: Chemistry
Publication Type :
Academic Journal
Accession number :
172774859
Full Text :
https://doi.org/10.1016/j.jphotochem.2023.115106