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Dissociative recombination of N2H+: a revisited study.

Authors :
Mezei, János Zsolt
Ayouz, Mehdi A.
Orbán, Andrea
Abdoulanziz, Abdillah
Talbi, Dahbia
Kashinski, David O.
Bron, Emeric
Kokoouline, Viatcheslav
Schneider, Ioan F.
Source :
European Physical Journal: Special Topics. Sep2023, Vol. 232 Issue 12, p1967-1973. 7p.
Publication Year :
2023

Abstract

Dissociative recombination of N 2 H + is explored in a two-step theoretical study. In a first step, a diatomic (1D) rough model with a frozen NN bond and frozen angles is adopted, in the framework of the multichannel quantum defect theory (MQDT). The importance of the indirect mechanism and of the bending mode is revealed, in spite of the disagreement between our cross section and the experimental one. In the second step, we use our recently elaborated 3D approach based on the normal mode approximation combined with R-matrix theory and MQDT. This approach results in satisfactory agreement with storage-ring measurements, significantly better at very low energy than the former calculations. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
19516355
Volume :
232
Issue :
12
Database :
Academic Search Index
Journal :
European Physical Journal: Special Topics
Publication Type :
Academic Journal
Accession number :
172311661
Full Text :
https://doi.org/10.1140/epjs/s11734-023-00922-5