Single-walled carbon nanotube interlayer modified gas diffusion layers to boost the cell performance of self-humidifying proton exchange membrane fuel cells.

A tradeoff between the low humidity and the high performance remains a key challenge for the proton exchange membrane fuel cell (PEMFC). In this work, a novel self-humidifying gas diffusion layer (GDL) with a single-walled carbon nanotube (SWCNT) nonwoven layer between the gas diffusion substrate and the hydrophobic microporous layer is controllably prepared to elevate the cell performance under dry conditions. The membrane electrode assembly (MEA) with 0.25 mg cm−2 SWCNT loading exhibits a current density of 0.69 A cm−2 at 0.6 V, which is 392.8% higher than that of the counterpart without the SWCNT interlayer at the same relative humidity. Moreover, the SWCNT interlayer with rational pore structure and proper wettability dramatically improves the water retention capacity of MEA, thus enhancing the low-humidity performance of MEA. The structure design of GDL provides an effective strategy for self-humidifying PEMFC control optimization. [Display omitted] • Self-humidifying GDLs are prepared by employing a SWCNT nonwoven interlayer. • Pore structure and wettability of GDLs are regulated by SWCNT loading. • Proper wettability of SWCNT layer mitigates ohmic and charge transfer resistances. [ABSTRACT FROM AUTHOR]