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Photoinduced copper-catalyzed selective three-component 1,2-amino oxygenation of 1,3-dienes.
- Source :
-
Chemical Communications . 9/7/2023, Vol. 59 Issue 69, p10388-10391. 4p. - Publication Year :
- 2023
-
Abstract
- This study presents a highly effective method for the photoinduced copper-catalyzed 1,2-amino oxygenation of 1,3-dienes. This synthetic strategy involves the dual roles of a single copper catalyst, which can act as a photosensitizer to generate nitrogen radicals and can also react with allyl radicals via single electron transfer (SET) processes. The method produces a range of quaternary carbon-centered allyl carboxylic esters and tertiary ethers with high yields and excellent regioselectivity under mild reaction conditions. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 59
- Issue :
- 69
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 170392982
- Full Text :
- https://doi.org/10.1039/d3cc02769d