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The effect of Al/oxidizers interfacial structure on the mechanical properties of composite propellants.
- Source :
-
Polymer Testing . Sep2023, Vol. 126, pN.PAG-N.PAG. 1p. - Publication Year :
- 2023
-
Abstract
- In this paper, the mechanical properties of a typical four-component composite solid propellants with various designed Al/oxidizer interfaces have been studied. The Al/oxidizer interfacial control is mainly realized by using the core-shell composites AP@Al and Al@RDX with different particle sizes, where Al powder was coated with a thin layer of polydopamine (PDA) as the binding sites, so that the oxidizers could crystalize on it during a rapid spray granulation process. The stress-strain curves of the above propellants at different temperatures and different tensile rates have been obtained. The dependence of the loss factor on temperature was studied by using a dynamic thermomechanical analysis (DMA). It has been shown that the fracture elongation of the interfacial modified propellants can reach 51.81% at room temperature, which is 127.3% higher than that of the blank formulation under the same formulation. Moreover, the temperature and strain rate sensitivity of interfacial controlled HTPB propellants is much less than that of traditional ones. The microstructure of these propellants at the crack sites was investigated by scanning electron microscopy (SEM) supported with micro-area in-situ tensile CT scanning technology, to clarify their damage and failure mechanisms. • Two types of core-shell Al-based composite fuels and corresponding solid propellants have been prepared. • The fracture elongation of the interfacial controlled solid propellants was improved significantly. • The temperature and strain rate sensitivity of these propellants are much less than those of traditional ones. • The fracture mode and damage evolution mechanisms of these propellants have been clarified. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01429418
- Volume :
- 126
- Database :
- Academic Search Index
- Journal :
- Polymer Testing
- Publication Type :
- Academic Journal
- Accession number :
- 170086322
- Full Text :
- https://doi.org/10.1016/j.polymertesting.2023.108167